Synthesis and characterization of a Pd Schiff base complex anchored on Fe3O4 as a novel and recyclable catalyst for C–C cross-coupling reactions

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Rahadian Zainul, Ali Basem, Mohamad J. Alfaker, Suhas Ballal, Talal Aziz Qassem, Irwanjot Kaur, M. Alaraj, Ayadh Al-khalidi, Yasser Elmasry

2024 Journal of Molecular Structure Vol. 1313 Article Cited by 12 Quartile

Abstract

Pd Schiff base complex was immobilized onto the surface of magnetic Fe3O4 as a novel, eco‐friendly, and recyclable heterogeneous catalyst and fully characterized by BET, TEM, XRD, EDS, SEM, TGA, FT-IR, ICP‐OES, and VSM techniques. The obtained Fe3O4@SiO2@APT@BDA@Schiff base-Pd performance can show excellent catalytic activity for C–C coupling reactions, and the corresponding products were obtained with high yields. The main advantages of using this catalyst include green reaction conditions, low loading of the catalyst, a simple experimental procedure, short reaction time, non‐use of hazardous organic solvents, and the ability to use various substrates. Palladium leaching was checked using ICP-OES and hot filtration. The synthesized nanocatalyst can be recovered and reused several times. The catalyst can be easily separated from the reaction mixture and recovered and reused without loss of stability and activity. © 2024 Elsevier B.V.

Affiliations

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Padang, Indonesia; Faculty of Engineering, Warith Al-Anbiyaa University, Karbala, 56001, Iraq; Department of Petroleum Engineering, Al-Amarah University College, Maysan, Iraq; Department of Chemistry and Biochemistry, School of Sciences, JAIN (Deemed to be University), Karnataka, Bangalore, India; Department of Medical Laboratory Technics, Al-Noor University College, Nineveh, Iraq; Department of Sciences, Vivekananda Global University, Rajasthan, Jaipur, 303012, India; Faculty of Pharmacy, Jerash Private University, Jerash, Jordan; Department of Medical Engineering, Al-Hadi University College, Baghdad, 10011, Iraq; Center for Energy and Power Electronics Research (CEPER), Universitas Negeri Padang, West Sumatera, Padang, Indonesia; Center for Advanced Material Processing, Artificial Intelligence, and Biophysics Informatics (CAMPBIOTICS), Universitas Negeri Padang, Padang, Indonesia; Research Fellow, INTI International University, Negeri Sembilan, Nilai, 71800, Malaysia; Central Labs, King Khalid University, AlQura'a, Abha, P.O. Box 960, Saudi Arabia; Department of Mathematics, Faculty of Science, King Khalid University, P.O. Box 9004, Abha 61466, Saudi Arabia