Siti Nur Akmar Mohd Yazid, Illyas Md Isa, Noorshida Mohd Ali, Norhayati Hashim, Mohamad Idris Saidin, Mohamad Syahrizal Ahmad, Abdullah M. Asiri, Anish Khan, Rahadian Zainul
A novel electrochemical sensor for sensitive and selective detection of hydroquinone (HQ) was developed using graphene/iridium(III) dimer complex composite modified glassy carbon electrode (graphene/Ir(III) complex/GCE). The composite was characterised by field emission scanning electron microscopy, energy dispersive X-ray microanalysis, Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. The graphene/Ir(III) complex/GCE has provided higher surface area which was good for catalytic activity and enhanced electrical conductivity that was then examined using differential pulse voltammetry, cyclic voltammetry, and square wave voltammetry. At optimal condition, HQ has been sensitively detected in the ranges of 100–1.5 µM and 1.5–0.05 µM with good sensitivity of 1120.64 μA/mM/cm2 and low detection limit of 1.1 nM (S/N = 3). The graphene/Ir(III) complex/GCE sensor presented the performance advantages of good reproducibility, repeatability, stability and selectivity. The prepared electrode was further applied to detect HQ in real-life water samples, which exhibit the acceptable recovery. © 2020 Informa UK Limited, trading as Taylor & Francis Group.
Department of Chemistry, Faculty of Science and Mathematics, Universiti Pendidikan Sultan Idris, Tanjung Malim, Malaysia; Nanotechnology Research Centre, Faculty of Science and Mathematics, Universiti Pendidikan Sultan Idris, Tanjung Malim, Malaysia; Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah, Saudi Arabia; Department of Chemistry, Faculty of Mathematics and Natural Science, Universitas Negeri Padang, West Sumatera, Indonesia
