Nurul Syahida Mat Rais, Illyas Md Isa, Norhayati Hashim, Mohamad Idris Saidin, Siti Nur Akmar Mohd Yazid, Mohamad Syahrizal Ahmad, Rahadian Zainul, Suyanta, Siriboon Mukdasai
A novel zinc/aluminium-layered double hydroxide-2-(2,4-dichlorophenoxy) propionate (Zn/Al-LDH-DPPA) nanocomposite to modify with multi-walled carbon nanotube (MWCNT) paste electrode for simultaneously determination of uric acid and bisphenol A. The Zn/Al-LDH-DPPA/MWCNT morphology was carried out by a scanning electron microscope and transmission electron microscope, electrode-electrolyte interface properties were examined by electrochemical impedance spectroscopy, and electrochemical responses thoroughly investigated by square-wave voltammetry. The electrode established linear plot for uric acid and bisphenol A from 5.0 x 10-6 M to 7.0 x 10-4 M (R2 = 0.9980) and (R2 = 0.9960) and the detection limits were 7.95 x 10-7 M and 8.71 x 10-7 M (S/N=3). The as-prepared sensor is reproducible, highly stable, sensitive as well as ascribed good anti-interference ability. The Zn/Al-LDH-DPPA/MWCNT electrode is applicable to evaluate simultaneously determination of UA and BPA in lake, river and, urine samples with good percentage recovery. © 2019 The Authors.
Department of Chemistry, Faculty of Science and Mathemathics, Universiti Pendidikan Sultan Idris, Tanjong Malim, Perak, 35900, Malaysia; Nanotechnology Research Centre, Faculty of Science and Mathemathics, Universiti Pendidikan Sultan Idris, Tanjong Malim, Perak, 35900, Malaysia; Department of Chemistry, Faculty of Mathematics and Natural Science, Universitas Negeri Padang, West Sumatera, 25171, Indonesia; Deparment of Chemistry Education, Faculty of Mathematics and Natural Science, Yogyakarta State University, Indonesia; Department of Chemistry, Faculty of Science, Khon Kaen University, Khon Kaen, 40002, Thailand
